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Calculation method
The following relations exist among mass and volume of solution, etc.
Ma = VaDcWc/100, Mb
= Vb+VaDc(100-Wc)/100, W
= 100Ma/M,
M = Ma+Mb = VaDc+Vb
= VD, C = 1000Ma/FV, Q = V/Vb, 1L
= 1000mL
where Va(mL), Wc(%) and Dc(g/mL) are volume,
mass percentage and density of conc. NH3 water before dilution, Ma(g)
mass of dissolved NH3 gas, Vb(mL) volume of diluent water
before dilution, Mb(g) mass of total water, M(g), V(mL), W(%), C(mol/L),
and D(g/mL) mass, volume, mass percentage, molarity, and density of solution after
dilution, Q volume of solution after dilution/volume of diluent water before dilution,
F(g/mol) formula weight of NH3.
An unknown value can be calculated with the use of relations shown above and known
values.
You may use the upper table to convert concentration to density, volume of solution/volume
of diluent water to concentration.
Preparetion method
Wash and dry apparatus beforehand.
1 Measure disstilled water with a
measuring cylinder, and transfer the water to a beaker.
2 Measure conc. NH3 water with another measuring
cylinder, and add slowly into the beaker with stirring.
3 If you need, transfer the solution to reagent bottle and attach label
showing the reagent's name, concentration, date, the person who prepared.
Caution
Ammonia gas evaporates from conc. ammonia water to the space (air) avobe the solution
in a bottle. So, the bottle of conc. ammonia water is filled with NH3
gas. When you open the cover spray may appear. Be careful for neither
gas nor mist to get in contact with the eyes. Moreover, there is toxicity
in the gas and it has a extremely pungent smell. Deal with it in a well
ventilated place so that gas may not be inhaled.
If conc. ammonia water gets in contact with the eyes or is stained with the skin,
immediately wash it with water.
The presumed concentration of reagent grade chemicals is near saturation (about
28%). When the exact concentration of dilute ammonia water is required,
titrate it against a solution of an acid of known concentration, a standard solution;
then, you can determine its exact concentration.